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Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to assemble nonlinear-optical exceptional-earth oxythiogermanatesThis can be a preview of subscription articles, log in through an institution to check access. Access this information(LIDT) and optical birefringence is The main element t

′�?, which has a frequency of 295 cm−one, is attributed towards the stretching vibration of Ga–Se bonds. The two-phonon absorption of your 295 cm−1 phonon corresponds on the crystal IR absorption edge, rather then the residual absorption peak. Density useful idea computations present that the residual absorption on the BGSe crystal origin